Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. This paper aims to explore the corrosion resistance of some stainless steels in. Stress corrosion cracking in duplex stainless steel. But once the passive film is overwhelmed by the increase in temperature, corrosion rate increases rapidly. The chloride ion cl is the most common of these and is found in everyday materials such as salt and bleach. Stresscorrosion cracking is a delayed failure process. The sequence of events involved in the scc process is usually divided into three stages. Corrosion resistance of stainless steels corrosion in concrete corrosion problems are not limited to outside surfaces. Pitting corrosion is a localized form of corrosion by which cavities or holes are produced in the material.
Stainless steel, due to its superior corrosion resistance relative to most other metals, such as carbon steel and aluminum, becomes the cathode, accelerating the corrosion of the anodic metal. It requires a susceptible material and, depending on the material, sufficient levels of. The effect of salt loading on chlorideinduced stress corrosion cracking in 304 l was studied at atmospheric pressure. A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. Now, stainless steel can be treated so that it lasts longer and experiences less trauma. An example is the corrosion of aluminum rivets fastening stainless steel sheets in contact with water. Feb 28, 2018 however, when introduced to chlorides, it tends to suffer stress corrosion cracking fairly quickly.
Oct 21, 2019 chloride stress corrosion cracking is a localized corrosion mechanism like pitting and crevice corrosion. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Jul 31, 2017 presumably, the corrosion products of both ductile iron and carbon steel were influenced by the level of chloride concentrations, which in turn reflected the variations in corrosion reactions. Pitting corrosion and stress corrosion cracking of. While its tensile strength is not at the level of austenitic stainless steel, ferritic stainless steel is. Boilersafe level of chlorides and other compounds in water. Chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Stainless steel provides both strength and corrosion resistance inside the concrete, providing a long, maintenancefree service life of the structure. High performance stainless steels nickel institute. As mentioned previously, stainless steels protective film is less effective when the oxide surface layer becomes damaged or scratched, which can cause corrosion in those areas. C are not recommended for 304 or 316 as they are at risk of sudden failure from chloride stress corrosion cracking. Chloride stress corrosion cracking in austenitic stainless steel. As temperature increases, and as long as the passive film remains intact, corrosion rate does not increase. Stress corrosion cracking of an austenitic stainless steel in.
It is difficult to control the temperature, while changing pipe material or eliminating residual stresses associated with welding and forming the pipework is costly and. The passive layer on stainless steel can be attacked by certain chemical species. Selection of stainless steels for handling chlorine. Corrosion of stainless steel in sodium chloride brine. I know ive seen here and elsewhere that below 200250ppm sulphates is generally safe for stainless steel, but ive not seen anything related to chlorides. Chloride stress corrosion cracking ssina specialty steel. Chloride corrosion of carbon steel pipe engineering. One of the most important forms of stress corrosion that concerns the nuclear industry is chloride stress corrosion. The risk for corrosion in brines is associated with the chloride content, temperature, ph and oxygen level. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion.
Temperature and corrosion rate more complex than you. Chlorides leachable level can be as little as 10 ppm, even though chlorides are contained within insulation materials. The 304 austenitic stainless steel was experimented in acid hydrogen chloride aqueous solution with mixing ratio 1. Pitting corrosion is avoided by making sure that stainless steel does not come into prolonged contact with harmful chemicals or by. They are subject to crevice corrosion and pitting in chloride containing environments and are also. Because mild steel was not included in this research study, further implementation of findings from this report will be delayed until an additional study on the conosive effects of magnesium chloride on mild steel is completed. Duplex stainless steel having attractive combination of austenitic and ferritic properties is being used in industry such as petrochemical, pulp and paper mills. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides. Stress corrosion cracking scc is a common issue with many specialty alloys. The effect of salt loading on chlorideinduced stress. Three general classifications are used to identify stainless steels. Design guidelines for the selection and use of stainless steel nidl distributed by. To take another example of chloride scc of austenitic stainless steels, tube and shell heat exchangers are frequently constructed using stainless steel tubes since these must be thinwalled and corrosion cannot be tolerated with carbon steel tube plates and shell since these can be made much thicker to provide a corrosion allowance.
Higher levels of chloride might cause crevice corrosion and pitting. Austenitic stainless steel ss type aisi 316l is being used to manufacture waste containers for radioactive intermediate level waste ilw in the uk. These steels can be heat treated to high strength levels. The test material 316l stainless steel was received in rolled plate. Stress corrosion cracking scc of austenitic stainless steels of types 316 was. Chloride stress corrosion cracking and 316 stainless steel. Stress corrosion cracking in duplex stainless steel great. Effect of chloride deposition on stress corrosion cracking.
Harsh pitting corrosion is a localized damage that eats pits into stainless steel. Together, chlorine and chloride cause stainless steel failures that wouldnt occur by exposure to chlorine or chloride alone. Chloride induced stress corrosion cracking ciscc of stainless steel reactor components has occurred when three elements are all present. To evaluate chlorideinduced stress corrosion cracking of type 304 stainless steel, corrosion 2012, march 1115, 2012, salt lake city, ut, agencywide documents access and management system adams accession no. Susceptibility assessment criteria for chlorideinduced. Tp304 ss and tp316 ss can occur when water containing chloride is present underneath insulation, external metal skin temperature exceeds approximately 50 c, and there is no surface protection or when the protective coating e. This series of stainless steels grade is commonly referred to as precipitation hardening stainless steels.
In addition to chloride ion, can be caused by elevated temperatures for extended. Ordinarily we would specify 316l stainless steel to limit the corrosion, but i was asked if we could instead specify carbon steel pipe with a corrosion allowance. Behaviour of stress corrosion cracking of austenitic. The investigation of austenitic stainless steel attacked by acid chloride containing environment was done. Higher temperatures reduce the permissible chloride level. What is the minimum concentration of chloride ion required. Stress relieved samples were uniaxially prestrained to 5% and were loaded with nine levels of mgcl 2, investigating cl. The steel was manufactured before 1970 with possible higher levels of. Clscc chloride stress corrosion cracking mechanism china. For example, chloride stress corrosion cracking of austenitic stainless steel has been experienced in hotwater jacketed pipes carrying molten chocolate in the food industry. Selection of stainless steels for handling chlorine cl2.
Effect of chloride deposition on stress corrosion cracking of 316l. However, when introduced to chlorides, it tends to suffer stress corrosion cracking fairly quickly. Salt water pools are high in free chlorides, which will cause chloride stress corrosion cracking in stainless steel heaters. When stainless steels are fully immersed, it is rare to see chloride stress corrosion cracking at temperatures below 60 c 150 f. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media. Corrosion of unprotected carbon steel occurs even inside reinforced. Cscc can attack highly resistant austenitic stainless steel. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of. External chloride stress corrosion cracking ecscc of insulated austenitic stainless steels e.
For this reason, stainless steels are being used in increasingly corrosive brine environments. Chloride cracking of 300 series stainless steels continues to occur in a number. Effect of chloride deposition on stress corrosion cracking of 316l stainless steel used for intermediate level radioactive waste containers. Figure 1 shows the cracking that occurred on a 6mo super austenitic stainless steel n08367 exposed to 0. With chloride containing environments and stainless steel, there is usually a threshold. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. The mechanism of chloride stress corrosion cracking clscc is complex and the current understanding is discussed in section 5 of this report.
Chloride stress corrosion cracking and 316 stainless steel moltenmetal chemical 20 jul 11 07. Modes such as pitting, crevice, stress corrosion cracking, sulfide stress corrosion cracking, integranular, galvanic, contact, passivation and pickling are covered. Im particularly interested in stainless steel, being my boiler is that material not sure what type of stainless steel. Environmental factors play an important role in how quickly corrosion develops as. Chlorine and chloride are different forms of the same element but with vastly different effects on stainless steel. However, the susceptibility of austenitic stainless steel to scc in a warm and oxygenated environment at certain chloride levels limits their use in many. The stainless will be ok at this level of salinity if at room temperature and neutral ph, but be cognizant of the risks to the carbon steel of galvanic corrosion and the buildup of fe concentrations, which are deleterious to stainless. Chloridechlorine levels and stainless steel alloy selection. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. Two main types of stainless steel corrosion are of particular concern in water system applicationscrevice corrosion. Stainless steel grades 600 series this series of stainless steels grade is commonly referred to as precipitation hardening stainless steels. Essentially clscc involves a combination of the electrochemistry of metal dissolving over a highly localised area, i. This level of chloride is considered to be the limit for the 188 alloys, particularly if crevices are present.
Key word environment, winter maintenance, deicing, magnesium chloride, sodium chloride, corrosion 18. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. A novel accelerated test for chloride stress corrosion cracking designed for austenitic stainless steel is presented. The combination of tensile stress and a specific corrosive environment can crack stainless steels. Reference is often made to stainless steel in the singular sense as if it were one material.
What is the maximum chloride in ppm that can be allowed in. Monitoring of chloride stress corrosion cracking of. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. All three families of the highperformance stainless steels will deliver a wide range of resistance to chloride pitting and stress corrosion cracking superior to that of types 304 and 316. Copper heaters will react with the salt water and turn the pool green. Stainless steel bellows which typically have high stress levels come in contact. The resistance of austenitic stainless steels to scc is related to the nickel. There is a synergistic relationship between dissolved oxygen and the chloride level. Stress corrosion cracking the international institute of. Chloride ion is the most common of these and is found in everyday materials such as salt and bleach. Stress corrosion cracking facts and how to reduce the risk. Effects of deicing agents magnesium chloride and sodium.
Chloride stress corrosion cracking in austenitic stainless. This mode of attack is termed stress corrosion cracking scc. That is, cracks initiate and propagate at a slow rate for example, 10 to 10 ms until the stresses in the remaining ligament of metal ex ceed the fracture strength. Effect of ph and chloride contents on stress corrosion. External applied stress by ubending was also applied to specimen in order to further study stress corrosion cracking phenomenon. In this study, the corrosion and stress corrosion behavior of duplex stainless steel in 3. Stress corrosion cracking of sensitized type 304 stainless. Chlorine in contact with water and as a dissolved gas, sometimes found in water treatment applications, is potentially aggressive to stainless steels. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. The typical crack morphology for chloride stress corrosion cracking consists of branched transgranular cracks. They are subject to crevice corrosion and pitting in chloride containing environments and are also subject to stress corrosion cracking and hydrogen embr ittlement.
The influence of chloride content, ph and temperature of test solution on the. Chloride stress corrosion cracking clscc is one the most common reasons why. Stainless steels are corrosionresistant, but to take full. Stress corrosion cracking, austenitic stainless steels, sodium chloride 1. Stress corrosion cracking international institute of. Chloride stress corrosion cracking inspectioneering. So instead of the typical schedule 40 pipe, could i realistically use schedule 80 or 120 etc. Chloride stress corrosion cracking in austenitic stainless steel chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. So instead of the typical schedule 40 pipe, could i. This makes it insufficient for purposes in which excess amounts of chloride are present. Effect of chloride deposition on stress corrosion cracking of. Jan 08, 2002 while stainless steels are often used for their corrosion resistance, they do in fact suffer from corrosion under certain circumstances. A precursor of stress corrosion cracking in chloride bearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting.
Chloride corrosion of carbon steel pipe engineering stack. Chloride level in carbon steel pipes corrosion engineering. Introduction stainless steel is often perceived as the backbone of modern industry 1. Although no stainless steel grade is totally immune.
Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Presumably, the corrosion products of both ductile iron and carbon steel were influenced by the level of chloride concentrations, which in turn reflected the variations in corrosion reactions. Does anyone know if theres a generally safe level of chlorides in water that shouldnt cause corrosion in metals. Pitting corrosion the passive layer on stainless steel can be attacked by certain chemical species.
The 304 and 304l 188 stainless steel alloys have been utilized very successfully in fresh waters containing low levels of chloride ion of up to 100 ppm. Corrosion protection coatings are beneficial for thermally. Guidelines for using stainless steel in the water and. What forms of corrosion can occur in stainless steels. On the stress corrosion cracking of lean duplex steel in. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. Pitting is considered to be more dangerous than uniform corrosion damage because it is more difficult to detect, predict and design against.
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